Quantitative Analysis of Relationship between Hansen Solubility Parameters and Properties of Alkali Lignin/Acrylonitrile–Butadiene–Styrene Blends

Blends of alkali lignin and acrylonitrile–butadiene–styrene (ABS) resin are physically mixed and injected into the injection molding system. Although the components of the blend are bound together by intermolecular forces, noticeable phase separation still occurs. In the present study, inverse gas chromatography technology was used to characterize the Hansen solubility parameters of alkali lignin/ABS blends. The relationship between the Hansen solubility parameters and thermodynamic properties was then determined. Hansen solubility parameters, at room temperature, of alkali lignin/ABS blends containing 0, 10, 20, and 30 wt % alkali lignin were 17.40, 19.20, 18.98, and 17.37 (J/cm3)0.5, respectively. Hansen solubility parameters of the blends were shown, both experimentally and theoretically, to be related to their mechanical and thermal properties.