Efficient hydrogen evolution and rapid degradation of organic pollutants by robust catalysts of MoS2/TNT@CNTs

Exploiting an inexpensive and high-effective composite catalyst for electrocatalytic hydrogen evolution and elimination of organic contaminant from wastewater has drawn great attentions recently. Herein, a facile two-step hydrothermal process was successfully adopted to realize the growth of MoS 2 nanosheet on the surface of unique TNT@CNTs (TC). Remarkable, the optimized MoS 2 /TNT@CNTs (MTC) catalyst exhibited high-efficient photocatalytic activity for high concentrations (30 mg/L) of methylene blue (MB) and rhodamine B (RhB) with the photodegradation rate of 98.7% and 99.0% in 50 min, which are 2 and 6 times higher than that of pure TiO 2 nanotube (TNT), respectively. Meanwhile, the novel composites also showed better hydrogen evolution reaction (HER) activity with the overpotential of 110 mV. The significant enhance in photocatalytic performance and electrocatalytic activity are attribute to formation of chemical bonds and large specific surface area, which effectively separate and transfer interfacial charges. The radical scavenging techniques confirmed that the holes (h + ) and •O 2 − radicals played a main role in the photocatalytic process. This study suggests that the novel nanocomposite has extensive application to solve environment and energy issues due to the low-cost raw materials, simple and inexpensive synthesizing process and environmental-friendly methods.