Optimal co-catalytic effect of NiFe2O4/ZnO nanocomposites toward enhanced photodegradation for dye MB

A series of magnetically recyclable NiFe 2 O 4 /ZnO nanocomposites have been successfully fabricated by a facile two-step route. The as-prepared NiFe 2 O 4 /ZnO nanocomposites were characterized by X-ray diffraction, field-emission scanning electron microscopy, vibrating sample magnetometer, ultraviolet-visible diffuse reflectance spectroscopy and photoluminescence spectroscopy. The results demonstrate that the NiFe 2 O 4 /ZnO nanocomposites are composed of ZnO particles (50–120 nm) integrated with NiFe 2 O 4 particles (30–80 nm) . Compared with bare ZnO, the NiFe 2 O 4 /ZnO nanocomposites exhibit evidently enhanced visible light absorption and decreased recombination of photo-generated electron-hole pairs. Moreover, the nanocomposites exhibit enhanced photocatalytic performance for the degradation of methylene blue under simulated solar light irradiation when compared with bare ZnO, and the 20%-NiFe 2 O 4 /ZnO nanocomposite is observed as the optimal composite. This is ascribed to the more efficient separation of photo-generated electron-hole pairs and generation of hydroxyl (˙OH) radicals in the 20%-NiFe 2 O 4 /ZnO nanocomposite. Furthermore, the NiFe 2 O 4 /ZnO nanocomposites have a high saturation magnetization, indicating that they can be magnetically separated and recycled from organic dye wastewater.