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One-pot synthesis of CuPt nanodendrites with enhanced activity towards methanol oxidation reaction

Journal 2018 · IF 2.936 · 8(17): 9293-9298 · 发表于 2018 年 3 月 5 日
作者: Hongcheng Peng,Weihong Qi,Haofei Wu,Jieting He,Yejun Li,Haipeng Xie
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摘要

CuPt nanodendrites have special electrocatalytic performance due to their unique morphologies and structures. In this work, we report a facile and one-pot synthesis of highly branched and dispersed CuPt nanodendrites with a size of about 22 nm and Pt/Cu ratio of 2 : 1. X-ray photoelectron spectra indicate a Pt-rich surface of the prepared CuPt nanodendrites. The combination of a highly branched structure with a Pt-rich shell would be very beneficial for catalytic properties, which was confirmed by electrochemical tests towards MOR. A systematic study on morphology evolution of the products and understanding of their growth mechanism was carried out using the effects of reaction time and reducing agents.

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