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Broadband white-light emission with a high color rendering index in a two-dimensional organic–inorganic hybrid perovskite

Journal 2017 · IF 5.256 · 6(5): 1171-1175 · 发表于 2017 年 12 月 18 日
作者: Zhenyue Wu,Chengmin Ji,Zhihua Sun,Sasa Wang,Sangen Zhao,Weichuan Zhang,Lina Li,Junhua Luo
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摘要

Two-dimensional (2D) organic–inorganic hybrid layered perovskites have attracted increasing attention as promising candidates in optoelectronics, due to their excellent physical attributes. However, although great efforts have been made, broadband white-light emission with a high color rendering index based on 2D hybrid perovskites still remains rare. Here, we report a broadband white-light emissive 2D organic–inorganic hybrid (110)-oriented perovskite, N-(3-aminopropyl)imidazole tetrachloro-lead (1), in which the 2D corrugated layered inorganic framework is formed by corner-shared highly distorted lead chloride octahedra. Remarkably, the color rendering index of 1 is up to 93, which is superior to that of previously reported broadband white-light emission in 2D organic–inorganic hybrid perovskites. Such a 2D hybrid layered perovskite material with a high color rendering index may provide potential applications in white light-emitting diodes.

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