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Preparation of Surface Imprinted Polymer D301-g-IIPDMC and its Recognition Selectivity Performance towards AuCl4−

Journal 2017 · IF 0.602 · 39(1): 58-64 · 发表于 2017 年 12 月 1 日
作者: Min Li,Xiao-yan Xue,Yong Wang,Fu-qiang An,Tuo-ping Hu,Jian-feng Gao
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摘要

In this article, a new surface imprinted polymer D301- g -IIPDMC is successfully prepared using AuCl 4 − as a template. The adsorption and recognition performances of D301- g -IIPDMC for AuCl 4 − are studied by using a static method and competitive adsorption experiment. The experimental results show that D301- g -IIPDMC possesses very strong adsorption affinity and excellent recognition for AuCl 4 − . The adsorption capacity of D301- g -IIPDMC for AuCl 4 − is 831.08 mg/g, and the selectivity coefficient relative to CuCl 4 2− is 128. The adsorption behavior is an endothermic spontaneous process, and fit well with pseudo-second order kinetic model and Freundlich adsorption isotherm model. Besides, D301- g -IIPDMC is desorbed easily and exhibits excellent reusability.

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