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Fe-N-doped porous carbon from petroleum asphalt for highly efficient oxygen reduction reaction

Journal 2017 · IF 6.337 · 发表于 2017 年 10 月 3 日
作者: Jingyan Liu,Yang Liu,Peng Li,Luhai Wang,Haoran Zhang,Hui Liu,Jialiang Liu,Yixian Wang,Wei Tian,Xiaobo Wang,Zhongtao Li,Mingbo Wu
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摘要

Fe-N-doped porous carbon derived from petroleum asphalt (NPCA) was prepared via a facile template synthesis method, with urea as nitrogen source while α-Fe 2 O 3 nanoparticles as template and Fe source. The as-prepared NPCA calcined at 900 °C (NPCA-900) exhibits excellent electrocatalytic performance with high diffusion-limiting current density and stability comparable to those of commercial Pt/C catalysts in alkaline environment . The remarkable ORR performance of NPCA could be ascribed to the abundant porosity, large specific surface area (1060 m 2  g −1 ), as well as the doping of Fe-N (especially pyridinic N). The NPCA derived from cheap petroleum asphalt has good application future in the field of catalysis, while it may pave a new way to realize the clean and high value utilization of heavy oils.

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