摘要
The TiAl/TiB 2 metal matrix composites (MMCs) are fabricated by selective laser melting (SLM), and the effects of scan line spacing on the grains feature, crystallographic texture, phases evolution mechanism and nanohardness have been systematic studied. With the increase of scan line spacing, relatively coarse grains with average grain size of 4.9 ± 0.2 μm and strong ( 0001 ) orientation gradually transforms into refined grains with average grain size of 4.2 ± 0.1 μm and dominated ( 11 2 ¯ 1 ) and ( 01 1 ¯ 1 ) orientations during the SLM process. The SLM-processed TiAl/TiB 2 MMCs samples are dominated by high-angle grain boundaries (HAGBs) and α 2 phase, with the increase of scan line spacing from 80 μm to 140 μm, both the volume fraction of HAGBs and α 2 phase decrease. During the SLM process, the phases evolution mechanism of TiAl/TiB 2 MMCs can be expressed as: (200)β first transformed to (11 2 ¯ 0)α 2 , (20 2 ¯ 0)α 2 and (110)γ, then the TiB 2 , residual B 2 and incompletely transformed γ phases randomly distribute in the α 2 matrix, and the orientation relationship of the α 2 , γ, B 2 and TiB 2 phases can be concluded as: ( 11 2 ¯ 0 ) α 2 // ( 110 ) B 2 // ( 110 ) γ// ( 110 ) TiB 2 . Besides, there are some TiB phase in the TiAl/TiB 2 MMCs which is induced by the Ti + TiB 2 → 2TiB reaction during SLM. The TiAl/TiB 2 MMCs samples show an ultra-high nanohardness ranging from 8.6 ± 0.4 GPa to 9.4 ± 0.5 GPa with the increase of scan line spacing, which is superior than that of the TiB 2 reinforced TiAl alloy counterpart (6.7 ± 0.4 GPa) fabricated by traditional roll bonding.
危险品化学品经营许可证(带存储)