Synthesis of poly(m-phenylenediamine)-coated hexagonal Co9S8 for high-performance supercapacitors

Poly( m -phenylenediamine)-coated hexagonal Co 9 S 8 was firstly synthesized by the polymerization with self-prepared hexagonal Co(OH) 2 used as cobalt source, and the calcination with sulfur powder providing sulfur source. By adjusting the concentration of m -phenylenediamine in the polymerization process, the coating was achieved with the different coated results, further affecting their supercapacitor behaviors by improving diffusion path for fast electron transfer. The resulting Co 9 S 8 /PmPD electrodes demonstrate excellent electrochemical performance with high specific capacitance of 950.1 F g −1 at a current density of 0.5 Å g −1 , good rate performance of 81.1% capacitance retention as the current density grows from 0.5 to 20 Å g −1 , and almost no capacitance loss after 1000 cycles. Moreover, as asymmetric positive electrode material, the Co 9 S 8 /PmPD-1 shows high specific capacitance of 115.3 F g −1 at 0.5 Å g −1 , outstanding rate performance of 78.2% capacitance retention even increased to 20 Å g −1 , superior cycle stability of 87.9% capacitance retention after 5000 cycles at 2 Å g −1 and largest energy density of 36.0 W h kg −1 at power density of 374.67 W kg −1 . This novel Co 9 S 8 /PmPD composite suggests a bright prospect for supercapacitor applications.