摘要
The α-Si 3 N 4 membrane was prepared by tape casting of silicon slurry, followed by calcination at 1300 °C in flowing NH 3 gas. It comprised of α-Si 3 N 4 nanowire of diameter 70 nm which were converted from silicon powder via the vapor–liquid–solid (VLS) growth mechanism. The surface of the obtained membrane was transformed from hydrophilic to superhydrophobic , with a high water contact angle of ~ 160°, by coating with a vesicular SiNCO nano-layer. The experimental results showed that nanowire structure also favored superhydrophobicity. Water desalination performance of the membrane was tested with a sweeping gas membrane distillation (SGMD) device. High water flux of 8.09 l m −2 h −1 was achieved for 20 wt% NaCl aqueous solution in the feed at 90 °C, which was maintained for more than 500 h.
危险品化学品经营许可证(带存储)