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Coupling reaction in catalytic decomposition of cyclohexyl hydroperoxide

Journal 2017 · IF 3.33 · 发表于 2017 年 8 月 1 日
作者: Xi Zheng,Jiping Ma,Min Wang,Song Shi,Zhiqiang Sun,Jie Xu
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摘要

Coupling reaction of cyclohexyl hydroperoxide (CHHP) decomposition and cyclohexane oxidation in the process of catalytic decomposition of CHHP was identified via cyclopentane instead of cyclohexane used as solvent. A method was established to evaluate this coupling reaction. Based on this method, it can be accurately distinguished the product of cyclohexanol and cyclohexanone (K/A oil) derived from whether decomposition of CHHP or oxidation of cyclohexane. The established method is of great significance to the further study of the coupling reaction.

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