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Strontium nitrate as a stable and potential anode material for lithium ion batteries

Journal 2017 · IF 2.986 · 发表于 2017 年 5 月 17 日
作者: Ke Yang,Hua Lan,Peng Li,Haoxiang Yu,Shangshu Qian,Lei Yan,Nengbing Long,Miao Shui,Jie Shu
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摘要

A novel anode candidate, Sr(NO 3 ) 2 , has been studied as a potential host material in lithium-ion batteries. The phase composition, particle morphology and lithium storage capability of Sr(NO 3 ) 2 have been thoroughly investigated. Sr(NO 3 ) 2 ,could maintain its reversible charge capacity at 237.3   mA   h   g −1 along with a high capacity retention of 99.08% at 50   mA   g −1 . Furthermore, it shows excellent cycling stability even at higher current density. Cycled at 500   mA   g −1 , it can deliver an initial charge capacity of 103.0   mA   h   g −1 kept at 100.9   mA   h   g −1 after 500 cycles. Compared with other nitrates that have been reported before, Sr(NO 3 ) 2 proved to have a better capacity retention capability at low and high rates. The high stable electrochemical performance can be ascribed to the absence of crystal water in its structure. Most importantly, commercial Sr(NO 3 ) 2 in this work just needs to be ground uniformly before its use as anode material and does not need complicated pretreatment like doping, carbon coating, calcination or nanocrystallization .

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