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Effects of the redox group of carbazole-EDOT derivatives on their electrochemical and spectroelectrochemical properties

Journal 2017 · IF 2.435 · 发表于 2017 年 5 月 9 日
作者: Bin Hu,Xinlei Zhang,Jin Liu,Xinxin Chen,Jiawei Zhao,Lin Jin
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摘要

Three novel monomers based on carbazole-3, 4-ethoxylenedioxythiophene and redox groups were synthesized and characterized. Their polymer films were obtained by electropolymerization. Cyclic voltammetry and spectroelectrochemistry of the polymer films showed that they possessed multi-electrochromic property. The presence of ferrocene and 2,2,6,6-tetramethyl-1-piperidinyloxy units not only changed the films’ colour but also improved their switching time due to their excellent electrochemical properties. Additionally, the polymer films also possessed a reasonable transmittance change, which made them promising candidates for use in electrochromic devices.

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