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An octupolar bis(porphyrinato) terbium(III) complex with the highest off-resonant hyperpolarizability

Journal 2017 · IF 3.108 · 7(37): 22855-22859 · 发表于 2017 年 4 月 25 日
作者: Junshan Sun,Yinfeng Han
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摘要

A novel bis(porphyrinato) terbium double-decker complex HTb(DADAPor)2 with a twisted cuboid octupolar molecular symmetry exhibits the largest off-resonant first hyperpolarizability, as evaluated by harmonic light scattering measurements with = 1700 × 10−30 esu.

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