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Cu3P/RGO promoted Pd catalysts for alcohol electro-oxidation

Journal 2017 · IF 3.133 · 发表于 2017 年 2 月 24 日
作者: Ke Zhang,Zhiping Xiong,Shumin Li,Bo Yan,Jin Wang,Yukou Du
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摘要

Herein, we reduced PdCl 4 2− ions on the synthetized cuprous phosphide/reduced graphene oxidation (Cu 3 P/RGO) hybrids to improve the catalytic activity and durability of Pd nanocrystals . In comparison with commercial Pd/C and Pd/RGO catalysts, the Pd/Cu 3 P/RGO exhibit high electroactivity and durability toward alcohol oxidation in alkaline medium. The enhanced catalytic performance of Pd/Cu 3 P/RGO is due to the high electrochemically active surface area, which can be ascribed to the interactions between Cu 3 P/RGO and Pd nanocrystals . The investigation of Cu 3 P/RGO as a promoter in alcohol electrooxidation will offer an opportunity in the field of direct alcohol fuel cells (DAFCs).

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