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Wormlike micelles with pH-induced rheological property formed by cationic surfactant/anthranilic acid mixed aqueous solution

Journal 2016 · IF 2.74 · 发表于 2016 年 10 月 4 日
作者: Wei Lin,Zhengming Yang,Juan Wang,Ting Chen,Xingwang Shi
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摘要

The pH-induced rheological property of octadecy trimethyl ammonium bromide with anthranilic acid was investigated. The viscoelasticity property and structural transformation of molecular self-assembly were comprehensively discussed by means of rheological measurements, dynamic light scattering and cryogenic-transmission electron microscopy. On the basis of surface tension results, the change of viscoelasticity was explained by calculating the packing parameter of P . UV–vis results confirmed that the pH-dependent interaction between the aromatic ring of anthranilic acid and the head group result in the transition between WLMs and spherical micelles, thus altering the viscoelasticity of WLMs.