Fabrication of 3D flower-like black N-TiO2-x@MoS2 for unprecedented-high visible-light-driven photocatalytic performance

As is well-known, it is a great challenge that the smooth TiO 2 nanospheres are coated by MoS 2 nanosheets to form the core-shell nanostructure owing to their poor interaction. Herein, we report 3D black N-TiO 2-x @MoS 2 core-shell nanostructures synthesized by a mild and effective strategy combined with a typical hydrothermal reaction and an in situ solid-state chemical reduction method followed by 350   °C calcination under an argon atmosphere. The prepared samples are characterized in detail by X-ray diffraction, Raman, scanning electron microscopy, transmission electron microscopy, and X-ray photoelectron spectroscopy. The results suggest that the 3D N-TiO 2-x @MoS 2 photocatalyst is successfully doped with N and Ti 3+ , and simultaneously coupling with MoS 2 to form the core-shell heterojunction nanostructure. The N and Ti 3+ co-doped and hybrid heterostructures can effectively utilize visible-light and solar energy to degrade methyl orange and produce hydrogen. The degradation rate of methyl orange and the hydrogen production rate are as high as 91.8% and 1.882   mmol   h −1   g −1 . To the best of our knowledge, this work is the first instance of combining MoS 2 with N and Ti 3+ co-doped TiO 2 , and the proposed photocatalytic mechanism will provide a new perspective for high activity photocatalyst in future.