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Synthesis of CoFe2O4/RGO nanocomposites by click chemistry and electromagnetic wave absorption properties

Journal 2016 · IF 1.798 · 27(9): 9278-9285 · 发表于 2016 年 5 月 19 日
作者: Liu Ziyu,Xu Guangliang,Zhang Ming,Xiong Kun,Meng Pingyuan
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摘要

Cobalt ferrite/reduced graphene oxide (CoFe 2 O 4 /RGO) nanocomposites were initially prepared by the interaction of alkyne-functionalized CoFe 2 O 4 NPs and azide-functionalized graphene oxide (GO–N 3 ) via the Cu (I)-catalyzed click reaction. The morphology and structure of CoFe 2 O 4 /RGO were investigated by means of XRD, FTIR, TGA, TEM, SEM and the electromagnetic parameters were measured by vector network analyzer. For CoFe 2 O 4 /RGO composites with click reaction, the minimum reflection loss could reach −40 dB at 6.8 GHz with a matching thickness of 4.0 mm, and also it had a bandwidth below −10 dB ranging from 5.8 to 8.5 GHz. The CoFe 2 O 4 /RGO composites with click reaction exhibited better microwave absorbing performance than the physical mixture. Furthermore, the covalent ligation between CoFe 2 O 4 NPs and graphene oxide could make the composites have a promising future in electromagnetic wave absorption materials.

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