Fabrication and properties of polyimide composites filled with zirconium tungsten phosphate of negative thermal expansion

Negative thermal expansion Zr 2 WP 2 O 12 (ZWP) powder prepared by hydrothermal method was used as fillers to tailor the thermal expansion coefficient (TEC) of the polyimide (PI)-based composites. A series of PI-based composites containing different loading (0–40 wt% or 0–19.6 vol%) of ZWP powder were fabricated by the in-situ polymerization technique. Their structures and properties were characterized by Scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FTIR), Impedance meter, Thermal mechanical analysis (TMA) and Thermogravimetric analysis (TGA). The additions of ZWP steadily reduced the TEC of the PI matrix at all loadings studied. A 40 wt% (19.6 vol%) ZWP loading gives a 32.5% (about 15 × 10 −6 /K) reduction of TEC. The thermal stability of the ZWP/PI composites can be enhanced with the increment of ZWP powder. The independence of the dielectric constant on frequency is improved by introduction of ZWP particles to PIs. The dielectric loss displays good stability, which indicates that the ZWP/PI composites show potential applications in microelectronic and aerospace industries .