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A novel recognition mechanism supported by experiment and theoretical calculation for hypochlorites recognition and its practical application

Journal 2015 · IF 4.097 · 发表于 2015 年 11 月 10 日
作者: Kangming Xiong,Fangjun Huo,Caixia Yin,Yueying Chu,Yutao Yang,Jianbin Chao,Anmin Zheng
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摘要

We have developed two new colorimetric and fluorescent probes for hypochlorite based on a novel recognition mechanism: amido oxidized nitroso-group by hypochlorites, which realized the preparation of nitroso compounds. Furthermore, 1 H NMR, ESI-MS and theoretical calculation proved the recognition mechanism. In addition, the probe 2 was applied in practical applications such as detecting the hypochlorite concentration of sodium hypochlorite disinfectant and bioimagings.

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