Reaction Kinetic Parameters and Surface Thermodynamic Properties of Cu2O Nanocubes

Cuprous oxide (Cu2O) nanocubes were synthesized by reducing Cu(OH)2in the presence of sodium citrate at room temperature. The samples were characterized in detail by field-emission scanning electron microscopy, transmission electron microscopy, high-resolution transmission electron microscopy, X-ray powder diffraction, and N2absorption (BET specific surface area). The equations for acquiring reaction kinetic parameters and surface thermodynamic properties of Cu2O nanocubes were deduced by establishment of the relations between thermodynamic functions of Cu2O nanocubes and these of the bulk Cu2O. Combined with thermochemical cycle, transition state theory, basic theory of chemical thermodynamics, andin situmicrocalorimetry, reaction kinetic parameters, specific surface enthalpy, specific surface Gibbs free energy, and specific surface entropy of Cu2O nanocubes were successfully determined. We also introduced a universal route for gaining reaction kinetic parameters and surface thermodynamic properties of nanomaterials.Keywords:nanothermodynamics;cuprous oxide;nanocrystal;specific surface enthalpy;specific surface Gibbs free energy;specific surface entropy