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A large-scale, green route to synthesize of leaf-like mesoporous CuO as high-performance anode materials for lithium ion batteries

Journal 2015 · IF 4.504 · 发表于 2015 年 2 月 6 日
作者: Zhongchao Bai,Yuwen Zhang,Yaohui Zhang,Chunli Guo,Bin Tang
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摘要

Herein, leaf-like CuO with mesoporous structure has been synthesized by treating commercial Cu(OH) 2 powder at room temperature for an appropriate time. The BET measurement shows that the obtained CuO has a high surface area of 23.55   m 2   g −1 and narrow pore distribution peaking at about 3.3   nm. The electrochemical performances of leaf-like mesoporous CuO are evaluated by cyclic voltammetry and galvanostatic charge-discharge studies. Electrochemical results show that the as-prepared CuO are promising anode materials in LIBs including high specific capacity, good retention and rate property. Even at the high current density of 2000   mA   g −1 , the mesoporous CuO electrode still can maintain a specific capacity of 490.5   mAh   g −1 which is much higher than the theoretical specific capacity of graphite (372   mAh   g −1 ).

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