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One-step pyrolytic synthesis of small iron carbide nanoparticles/3D porous nitrogen-rich graphene for efficient electrocatalysis

Journal 2015 · IF 7.443 · 3(9): 4976-4982 · 发表于 2015 年 1 月 16 日
作者: Hao Huang,Xun Feng,Cuicui Du,Siyuan Wu,Wenbo Song
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摘要

Uniform iron carbide nanoparticles (Fe3C, ∼10 nm), size evolved from nano-scaled Fe-MIL-88b, were one-pot pyrolytically embedded in 3D porous N-rich graphene. Extra ORR catalytic activity with four-electron selectivity was achieved in an alkaline electrolyte. The onset and peak potential were 10 mV and 40 mV more positive, respectively, than commercial Pt/C.

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