Fabrication of hierarchical structured SiO2/polyetherimide-polyurethane nanofibrous separators with high performance for lithium ion batteries

ABSTRACT The performance of lithium ion battery based on electrospun nanofibrous membranes has gained a great deal of attention in the past decades, but the intrinsic low mechanical strength and large pore size of electrospun membranes limit their battery performance. To overcome this limitation, a powerful strategy for designing, fabricating and evaluating silica nanoparticles coated polyetherimide-polyurethane (SiO 2 /PEI-PU) nanofibrous composite membranes is easily developed via electrospinning followed by a dip-coating process. Benefiting from the high porosity, interpenetrating network structure and synergetic effect of PU, PEI and SiO 2 nanoparticles, the as-prepared composite membranes exhibit high ionic conductivity (2.33   mS   cm −1 ), robust tensile strength (15.65   MPa) and improved safety (excellent thermal resistance and flame retardant property). Additionally, the as-prepared composite membranes possess relatively narrow pore size distribution with average pore size of 0.58   μm after coating SiO 2 nanoparticles, which plays an important role in hindering the micro-shorting and mitigating self-discharge. Significantly, the SiO 2 /PEI-PU membranes based Li/LiFePO 4 cell exhibits more excellent cycling stability with capacity retention of 98.7% after 50 cycles at 0.2   C rate and better rate capability compared with the Celgard membrane based cell. The results clearly demonstrate that this is a promising separator candidate for next-generation lithium ion batteries, which may represent a significant step toward separators with improved performance.