Advanced semi-interpenetrating polymer network gel electrolyte for rechargeable lithium batteries

A new type of semi-interpenetrating polymer network (Semi-IPN) gel polymer electrolyte (GPE) membrane based on the cross-linked poly(ethylene glycol) diacrylate- co -poly(vinylene carbonate) P(EGDA- co -VC) and PVDF-HFP linear polymer is successfully synthesized by UV-cured technology. The cross-linked P(EGDA- co -VC) can accommodate a large amount of liquid electrolyte inside the non-porous membrane via its strong interaction with Li + and solvents, which avoids the liquid electrolyte leakage. The ionic conductivity of the Semi-IPN GPE reaches 1.49   ×   10 −3   S   cm −1 at 25   °C and the electrochemical stability window up to 4.2   V (versus Li/Li + ). It demonstrates excellent interface stability to lithium metal electrode, superior thermal stability and good mechanical properties. A symmetric Li/Li cell with the above electrolyte displays a lower voltage polarization and longer valid cycle life than that based on conventional liquid electrolyte. Moreover, the Li/LiFePO 4 cells using the Semi-IPN GPE show superior cycling stability and rate performance comparable to the cell based on conventional liquid electrolyte. This Semi-IPN GPE is promising for rechargeable lithium batteries with high safety and energy density.