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Excess molar volume along with viscosity, refractive index and relative permittivity for binary mixtures of exo-tetrahydrodicyclopentadiene with four octane isomers

Journal 2014 · IF 2.423 · 发表于 2014 年 10 月 6 日
作者: Lei Yue,Xiaomei Qin,Xi Wu,Li Xu,Yongsheng Guo,Wenjun Fang
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摘要

The fundamental physical properties including density, viscosity, refractive index and relative permittivity , have been measured for binary mixtures of exo -tetrahydrodicyclopentadiene (JP-10) with four octane isomers ( n -octane, 3-methylheptane, 2,4-dimethylhexane and 2,2,4-trimethylpentane) over the whole composition range at temperatures T   =   (293.15 to 313.15)   K and pressure p   =   0.1   MPa. The values of excess molar volume V m E VmE , viscosity deviation (Δ η ), refractive index deviation (Δ n D ) and relative permittivity deviation (Δ ε r ) are then calculated. All of the values of V m E VmE and Δ η are observed to be negative, while those of Δ n D and Δ ε r are close to zero. The effects of temperature and composition on the variation of V m E VmE values are discussed. The negative values of V m E VmE and Δ η are conductive to high-density and low-resistance of fuels, which is favorable for the design and preparation of advanced hydrocarbon fuels.

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