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Facile synthesis of bimetallic alloyed Pt-Pd nanocubes on reduced graphene oxide with enhanced eletrocatalytic properties

Journal 2014 · IF 4.086 · 发表于 2014 年 8 月 10 日
作者: Jing-Jing Lv,Jie-Ning Zheng,Li-Li Chen,Meng Lin,Ai-Jun Wang,Jian-Rong Chen,Jiu-Ju Feng
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摘要

In this work, a one-pot solvothermal method was developed for large-scaled synthesis of well-defined bimetallic alloyed Pt-Pd nanocubes uniformly supported on reduced graphene oxide nanosheets (Pt-Pd nanocubes/RGOs). Herein, poly(vinylpyrrolidone) (PVP) and KI were employed as a capping agent and a structure-directing additive, respectively, and N , N -dimethylformamide (DMF) is used as a solvent and a reducing agent. The as-prepared Pt-Pd nanocubes/RGOs exhibited the enlarged electrochemically active surface area, enhanced electrocatalytic activity, and improved stability for ethanol oxidation reaction (EOR) and oxygen reduction reaction (ORR), compared with commercial Pt-C (10   wt %).

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