Tunable Mission and Trichromatic White-Emitting in Oxyfluoride Glasses by Utilization of Cu+ Ions as Multiple Energy-Transfer Creators

A series of copper species, Tb 3+ , Mn 2+ single- and co-doped oxyfluoride glasses were synthesized by a melt-quenching method. The photoluminescence properties of the glasses containing copper species were demonstrated. Results indicate that the blue-green emission band peaking at 440 nm was observed, which was ascribed to the photoluminescence of Cu + ions rather than the emissions of Cu 2+ cations or Cu nano-particles (Cu NPs) induced by local field effect (LFE) enhancement through surface plasmon resonance (SPR). The interaction mechanisms between Cu + and Tb 3+ /Mn 2+ have been systematically investigated, and significant enhancement of Cu + emission and the energy-transfer (ET) efficiencies of Cu + →Tb 3+ and Cu + →Mn 2+ were observed in glasses doped with SnO reducing agent. Furthermore, a wide-range-tunable emission and ideal white-light fluorescence were realized in Cu + /Tb 3+ /Mn 2+ -coactivated glasses by utilization of Cu + cations as dual ET contributors from deep-UV-source to multiactivators. Our research further extends the understanding of the interactions between Cu + and Tb 3+ /Mn 2+ in amorphous materials.