Micro-mesoporous carbon spheres derived from carrageenan as electrode material for supercapacitors

The polysaccharide carrageenan is used as a natural precursor to prepare micro-mesoporous carbon spheres. The carbon spheres were synthesized by hydrothermal carbonization of carrageenan, and subsequent chemical activation by KOH at different temperatures. The obtained micro-mesoporous carbon spheres have high surface area (up to 2502 m 2  g −1 ) and large pore volume (up to 1.43 cm 3  g −1 ). Moreover, the micro- and mesoporosity can be finely tuned be modifying the activation temperatures in the range of 700–900 °C. The carbon spheres activated at 900 °C present high specific capacitance of 230 F g −1 at a current density of 1 A g −1 and good ion transport kinetics. The good capacitive performance can be ascribed to the high specific surface area, well-controlled micro- and mesoporosity and narrow pore size distribution .