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ENHANCED VISIBLE-LIGHT-DRIVEN PHOTOCATALYTIC DEGRADATION PERFORMANCE OF CIP ON BiVO4–Bi2WO6 NANO-HETEROJUNCTION PHOTOCATALYSTS

Journal 2014 · IF 1.26 · 发表于 2014 年 4 月 3 日
作者: SHAOFANG SUN,YAFAN WU,XIAN ZHANG,ZHONGJIE ZHANG,YAN YAN,WEISHENG GUAN
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摘要

The removal of CIP from the environment has become a mandatory issue. In our paper, we have realized the visible-light-driven degradation of CIP on the BiVO 4 – Bi 2 WO 6 nano-heterojunction photocatalysts. The synthesized photocatalysts were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), ultraviolet-visible (UV-Vis) absorption spectra and photoluminescence (PL) spectra. Compared with the single-phase BiVO 4 and Bi 2 WO 6 counterparts, BiVO 4 – Bi 2 WO 6 nano-heterojunction photocatalysts show enhanced photocatalytic degradation activities in visible-light-driven CIP degradation. Particularly, when R ( Bi 2 WO 6 ∕ BiVO 4 ) = 10 wt .%, the products exhibit the highest CIP degradation ratio in 60 min of 76.8% under visible light illumination. The tentative mechanism of the interface charge transfer (IFCT) effect in the BiVO 4 – Bi 2 WO 6 heterojunction structure is also discussed by using the band position calculation.

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