Synthesis of g-C3N4/TiO2 with enhanced photocatalytic activity for H2 evolution by a simple method

A photocatalyst composed of graphite-like carbon nitride (g-C 3 N 4 ) and TiO 2 was fabricated by a simple method to calcine the mixture of melamine and TiO 2 precursor. The photocatalyst has enhanced photoactivity for hydrogen evolution from water. Characterization by XRD , FTIR, SEM and elemental analysis showed that the crystal structure and morphologies of composites were affected by the amount of melamine in the composite. The UV–Vis characterization displayed that the optical absorption range of g-C 3 N 4 /TiO 2 hybrid was broadened with a synergistic effect . The photoactivity for H 2 evolution was shown that the best result obtained from the composite with 67 wt% melamine has about 5 times improvement compared with bare TiO 2 or pure g-C 3 N 4 . The enhanced photoactivity might be related with the favorable structure resulted from heat-treatment temperature, and the content of g-C 3 N 4 participating in wide optical absorption, separation and transportation of electronic-holes, as well as morphology of composite.