A nanoparticle Mg-doped Li4Ti5O12 for high rate lithium-ion batteries

A nanoparticle Mg-doped Li 4 Ti 5 O 12 with a grain size of 20–30   nm has been successfully synthesized through a simple hydrothermal method . The first-principle simulations are employed to theoretically study the crystal structure, unit cell volume, lattice parameters , and band gaps. Galvanostatic charge–discharge tests have been carried out, using the as-prepared Li 4 Ti 5 O 12 and Mg-doped Li 4 Ti 5 O 12 as the working electrodes with a voltage range of 0.5–2.5   V vs. Li + /Li. The tests show promising results with high capacity and long term stability. When discharging at 350   mA   g −1 (corresponding to a 2   C rate), the discharge capacity remains at 170   mAh   g −1 over 100 cycles. As the C-rate rises to an ultrafast charge–discharge rate of 50   C, the discharge capacity can still retain at 115   mAh   g −1 . The excellent electrochemical performance is due to both the nanomorphology and better conductivity after Mg doping. The results show that the Mg-doped Li 4 Ti 5 O 12 can act as a fast charge–discharge anode material for high rate lithium-ion batteries (LIBs).