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Porous Si coated with S-doped carbon as anode material for lithium ion batteries

Journal 2012 · IF 2.131 · 17(4): 961-968 · 发表于 2012 年 11 月 25 日
作者: Yue Lu,Zhong Haoxiang,Tang Daoping,Zhang Lingzhi
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摘要

A novel porous Si/S-doped carbon composite was prepared by a magnesiothermic reaction of mesoporous SiO 2 , subsequently coating with a sulfur-containing polymer-poly(3,4-ethylene dioxythiophene), and a post-carbonization process. The as-prepared Si composite was homogeneously coated with disordered S-doped carbon with 2.6 wt.% S in the composite and retained a high surface area of 58.8 m 2  g −1 . The Si/S-doped carbon composite exhibited superior electrochemical performance and long cycle life as an anode material in lithium ion cells, showing a stable reversible capacity of 450 mAh g −1 even at a high current rate of 6,000 mA g −1 .

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