摘要
A carbonate-bridged rhodium(III) dimeric complex of formula μ-CO 3 -[(ppy) 2 Rh] 2 , (ppy = 2-phenylpyridine) was synthesized and characterized by IR and 1 H NMR spectroscopy as well as X-ray diffraction. The bridging carbonate ion presumably originates from the capture of CO 2 in air deduced on a series of control experiments, which may have valuable implications for the study of fixation of CO 2 . The luminescent and thermal properties of this complex were also investigated.
危险品化学品经营许可证（带存储）