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A quinoline colorimetric ionic liquid probe by electrostatic enhancement for visual detection of Fe3+ in food

Journal 2024 · IF 4.3 · 发表于 2024 年 11 月 30 日
作者: Siying Che,Xiutan Peng,Anbang Shen,Linlin Yin,Yuanbin She,Haiyan Fu
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摘要

Excessive or insufficient iron(Ⅲ) will pose burdens of human body, and its content is the key to control the function of iron-fortified food. In this regard, a functionalized quinoline ionic probe, benefiting from the electrostatic attraction, was designed for the colorimetric detection of Fe 3+ in food. This probe formed a 2: 1 complex with Fe 3+ , altering the UV–vis spectra and solution color. The UV–vis detection limit was 0.2 μM, and visually, the color shifted from light-yellow to dark-green as Fe 3+ concentrations increased, with a visual detection limit of 3.4 μM, meeting the maximum acceptable level of 5.4 μM. Noteworthy, ionic liquid-based sensing paper was constructed for rapid, semi-quantitative Fe 3+ detection. Furthermore, the satisfying recovery (97.4–102.9 %) was obtained in real samples, showcasing the probe’s efficiency. This work demonstrated the potential of ionic liquids for the fast, sensitive, and visual detection of Fe 3+ , offering a promising direction for metal element sensing platforms.

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