Alkali-Free Oxidation of 1,2-Propanediol to Lactic Acid over Intermetallic Cu1Pt Compounds

Polylactic acid (PLA) plastics are the most popular biodegradable and biocompatible materials; however, their monomer, lactic acid (LA), is currently produced via an inefficient fermentation process. Herein, activated carbon-supported Pt–Cu intermetallic compounds were synthesized and utilized in the selective oxidation of 1,2-propanediol (1,2-PDO) toward LA without the participation of homogeneous alkali or a basic support. It was found that rhombohedral intermetallic Cu1Pt compounds exhibited excellent performance and the calculated turnover frequency of each surface Pt atom reached 10 049 h–1. The yield of free LA reached 64.6% with a complete conversion of 1,2-PDO at 100 °C within 2 h. Diverse characterization and DFT calculations revealed that Pt–Cu intermetallic compounds were active for the adsorption and/or activation of molecular oxygen and 1,2-PDO. Raman analysis of adsorbed 1,2-PDO further disclosed that 1,2-PDO contacted with rhombohedral intermetallic Cu1Pt compounds strongly, and then the oxidation of the terminal hydroxyl group was performed preferentially, which promoted the formation of LA.