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An adaptive and fast emulsion separation Janus membrane

Journal 2024 · IF 7.1 · 发表于 2024 年 9 月 24 日
作者: Yuyan Guo,Zhiguang Guo,Weimin Liu
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摘要

Inspired by the capillary effect in nature (such as water transport in soils) and droplet-drive performance of Nepenthes, a new driving strategy for emulsion separation membrane based on the synergistic effect of capillary force and progressive wettability-induction force was proposed. It is prepared by a one-step, simple continuous, electrospinning process. By adjusting solutions and spinning parameters, the membrane obtains its capillary structure and progressive oleophilicity in one-step preparation. Attractively, the membrane shows separation efficiency and excellent permeability, with a flux of 384801 L m −2  h −1 bar −1 for the oil-water mixture, and the little water content of less than 18 ppm. And for emulsions, the flux even reaches 50000 L m −2  h −1 bar −1 and the separation efficiency reaches 99.95%. Furthermore, the membrane has excellent mechanical-stability: at 80 kPa transmembrane pressure, it can still effectively prevent water's penetration. Drawing inspiration from nature, the incorporation of capillary force and progressive wettability-induction force into the separation membrane as an additional dual emulsion separation driving force proves to be a highly effective and versatile approach. This method provides a way to solve the general flux-efficiency balance problem of oil-water separation and also provides a new strategy for the preparation of separation membranes for various purposes.

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