Co-grafting of polyethyleneimine on facilely synthesized mesoporous P(DVB-D) for highly effective CO2 adsorption and enhanced oxidation resistance

Solid amine adsorbents are showing promise as effective adsorbents for the capture of CO 2 from various gas mixtures, including biogas and flue exhaust gas. In this study, we introduced a co-grafting strategy using 1,4-butanediol diglycidyl ether (BDDE) on the surface of P(DVB-D). This approach aimed to exploit the reaction involving the opening of epoxy groups with amine groups, forming covalent bonds between polyethyleneimine (PEI) and mesoporous organic polymers, along with the introduction of hydroxy groups to enhance adsorbent long-term stability and antioxidation ability. After an extensive assessment, P(DVB-D)@B-41.2 %PEI exhibited a maximum CO 2 capture capacity of 4.53 mmol/g at 50 °C and 50 % RH. Notably, its remarkable CO 2 adsorption performance persisted across a diverse temperature spectrum (30–90 °C) and an extensive concentration span (5–30 % vol.). In contrast to conventional adsorbents prepared solely through impregnation methods, P(DVB-D)@B-41.2 %PEI exhibited impressive long-term stability throughout 50 successive cycles and excellent resistance to oxidative degradation. These findings underscore the considerable potential of P(DVB-D)@B-41.2 %PEI in the realm of carbon capture and sequestration (CCS) technology.