Coupling effects of dielectric loss in N-doped carbon double-shelled hollow particles for high-performance microwave absorption

Microwave absorbing materials with lightweight and high-performance are of great significance for electronic technique, ecological environment and defense applications. The hollow structure of carbon microspheres is beneficial to achievement of high-performance microwave absorption due to high interfacial polarization. However, the key characteristic is still unclear to control interfacial polarization. Herein, double-shelled N-doped carbon hollow particles derived from polypyrrole by self-sacrifice template were synthesized. The polymerization process was controlled by the interface between solid and pyrrole acid liquid in Fe 3 O 4 disperse system, subsequently, micro-nano structure of carbon was tuned. The N-doped carbon double-shelled hollow particles (DSHS) show a strong dielectric loss due to coupling effect of resistance loss and interfacial polarization owing to the double-shelled hollow structure. Thus, DSHS shows a high-performance microwave absorption with minimum reflection loss (RL min ) of −75.10 dB at a thickness of 2.48 mm and effective absorption bandwidth (RL ≤ -10 dB) of 6.08 GHz and 4.05 GHz covering the whole Ku band and almost the whole X with a thickness of 2.21 mm and 3.00 mm, respectively. This work provides a simple approach for synthesizing N-doped carbon particles with distinct micro-nano hierarchical structure, double-shelled hollow microspheres assembled by nanoparticles have potential application as a high-performance MAM.