Enhanced removal of trace thallium by photo-promoted adsorption using Prussian blue@filter papers: Performance and mechanistic insights

Developing highly efficient adsorbents for the removal of trace thallium(I) (Tl + ) is crucial for addressing environmental challenges. In this study, we successfully synthesized cubic Prussian blue (PB) loading on filter papers using an intermediate layer (dopamine/polyethyleneimine) via in-situ methods. The as-prepared PB-modified FP demonstrated outstanding anti-interference properties and light-enhanced adsorption performance for Tl + (0.5 mg/L) under ultraviolet (UV) irradiation, exhibiting twice the effectiveness compared to dark conditions, even in acidic and coexisting ionic environments. This indicated its suitability for treating complex Tl + -contaminated water. Notably, the removal efficiency for trace Tl + was almost 100%, with a maximum experimental adsorption capacity of 86.2 mg/g after 1-h photo-promoted adsorption under 365 nm UV. Characterization results supported a proposed photo-driven redox mechanism that elucidated the interaction between Tl + and PB-modified FP. Specifically, the accelerated Fe(III) to Fe(II) redox reaction facilitated Tl + accommodation on the surface and/or lattice of PB, enhancing Tl + adsorption by compensating for missed positive charges. This study provides valuable insights into utilizing PB-based materials to enhance the photo-enhanced Tl + adsorption capacity in a cost-effective, easy-to-synthesize, and environmentally friendly manner.