Excellent microwave absorption property of 3D printed SiCN matrix metamaterial

The combination of 3D printing , polymer derived ceramics, and electromagnetic wave (EMW) absorption metamaterials is particularly useful for spacecraft stealth in extreme environments and is gradually gaining significant interest. While the 3D printing of SiOC has been extensively researched, the high temperature stability and mechanical performance of SiOC are not as favorable as SiCN. However, it remains challenging to prepare SiCN metamaterials with both high mechanical and microwave absorption properties by 3D printing. Herein, we demonstrate a SiCN EMW absorption metamaterial with high mechanical properties using digital light processing 3D printing, which achieves a minimum reflection loss of −31.01 dB (99.9 % absorption), and the widest effective absorption bandwidth covers the entire X-band from 8.2 to 12.4 GHz. And the EMW absorption performance can be adjusted based on the size of the unit structure.