Fabrication of stable monolayer liquid marbles with reduced particle coverage and locomotion on hydrophilic surface

Liquid marbles are non-wetting, particle-covered microdroplets with a core-shell structure that are used in sample transport, material synthesis, and real-time sensing. Optimizing the distribution of shell particles remains a challenge, due to a tendency for aggregation via spontaneous assembly, which often leads to multilayered structures. Here, we outline a simple method for fabricating water-filled, monolayer liquid marbles with adjustable particle coverage rates, greatly reducing particle consumption. The soft liquid marbles are enclosed by a small quantity of modified polystyrene microspheres and display good atmospheric stability. The rolling behavior of flexible liquid marbles with wide coverage rates is then characterized. Contrary to common perception, the marbles with transparent openings exhibit high maneuverability on hydrophilic surfaces, and also excel in fusion, reaction and surface cleaning, with an elongated operational duration and a wide visualization range. The study provides new insights into the implementation of liquid marble-based miniaturized platforms.