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Flexible hollow Ni/Al2O3 fibers: A sustainable and reusable catalyst for efficient dry reforming of methane

Journal 2024 · IF 3.5 · 107(10): 6764-6773 · 发表于 2024 年 7 月 1 日
作者: Huihui Yan,Kun Wang,Liping Zhao,Peng Zhang,Han Chen,Jing Liu,Lian Gao
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摘要

A new type of Ni/Al 2 O 3 self-supporting catalysts, with high specific surface area, was fabricated by blow-spinning technology. These Ni/Al 2 O 3 self-supporting catalysts are hollow flexible fibers and were utilized for the dry reforming of methane. The Ni/Al 2 O 3 catalysts exhibited exceptional catalytic performance, maintaining their activity for over 150-h at a high temperature of 800°C. The Ni nanoparticles disputed on the hollow fibers demonstrated remarkable resistance to sintering and coking during high-temperature catalysis. This was a noteworthy feature, as sintering and coking are common challenges faced by catalysts during high-temperature reactions. Furthermore, the catalysts retained its activity even after a rigorous 150-h test at 800°C, indicating its durability and stability. Importantly, the Ni/Al 2 O 3 self-supporting could be successfully reactivated after the test, further highlighting its reusable nature. This study offers promising new avenues for the development of high-temperature, self-supporting, and reactivatable catalysts.

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