Fluorine-doped carbon dots decorated on iron-cobalt selenide nanosheets as superior electrocatalysts for oxygen evolution in seawater

Developing oxygen evolution reaction (OER) catalysts that can efficiently and stably operate at high current densities in seawater electrolysis is urgently demanded but challenging. In this study, selenium-vacancies-rich iron-cobalt selenide nanosheets (FeCoSe-V Se ) decorated with fluorine-doped carbon dots (FCDs) are rationally designed and prepared on nickel foams (NF) through the successive processes of hydrothermal treatment and selenization. Benefiting from the large accessible surface area and abundant active sites provided by FCDs and selenium vacancy defects, as well as the coupled interface between FCDs and FeCoSe-V Se that optimizes the oxygen adsorption energy and accelerates the kinetic process, the FCDs/FeCoSe-V Se /NF composite exhibits excellent OER catalytic activities with a low overpotential of 258 mV at a current density of 200 mA cm −2 in 1 M KOH and a small Tafel slope of 34.7 mV dec –1 . In the electrolytes of simulated and natural seawater, the overpotentials of the FCDs/FeCoSe-V Se /NF electrode are slightly higher, measured to be 264 and 297 mV, respectively. More profoundly, the introduction of FCDs enhances the corrosion resistance of the catalyst in alkaline electrolytes, ensuring the long-term stability. This work offers a guidance to improve the electrochemical performances of catalysts for high-efficiency seawater oxidation.