摘要
Separation membranes based on graphene oxide (GO) have attracted much attention due to their good separation properties. But its instability in water and rejection of divalent salt ions is a problem that needs to be solved urgently. In this study, molybdenum disulfide (MoS 2 ) is intercalated into graphene oxide by adding polyethyleneimine (PEI) solution drop by drop for cross-linking, and then GO/MoS 2 /PEI composite membrane is prepared by vacuum filtration. As MoS 2 hydrophobicity increases frictionless water flow channels to improve water flux, PEI cross-linking improves membrane stability and rejection of divalent salt ions. The modified composite membrane has a high rejection of 94.8 % for Mg 2+ , and water flux is increased by 30 % relative to GO/PEI membrane. In addition, the rejection of the composite membrane to different salt solutions is investigated by MgCl 2 , MgSO 4 , NaCl and Na 2 SO 4 solutions, and the results obtained are, in order, R(MgCl 2 ) > R(MgSO 4 ) > R(NaCl) > R(Na 2 SO 4 ). This modified composite membrane has great potential for salt ion removal.
危险品化学品经营许可证(带存储)