Lewis acid-rich SrFexTi1−xO3/TiO2 to enhance the photocatalytic reduction of nitrate to N2

The photocatalytic reduction of nitrate has received considerable attention due to its high efficiency and environmentally friendly nature. The excessive addition of hole scavengers is the most commonly used method to increase the nitrate reduction efficiency. However, achieving high selectivity in the photocatalytic reduction of nitrate to N 2 with low concentration of hole scavengers remains challenging. In this study, the SrFe x Ti 1−x O 3 /TiO 2 S-scheme heterojunction photocatalysts with many Lewis acidic adsorption sites have been developed. The experimental results demonstrated that the incorporation of 6% Fe into SrFe 0.06 Ti 0.94 O 3 /TiO 2 (SFTO6) resulted in the nitrate conversion rate of 97.68% and the N 2 selectivity reached 96.35% with 25 mmol/L formic acid . Moreover, it also exhibited excellent stability and recycle ability. After 5 cycles, SFTO6 still exhibited a stable photocatalytic denitration efficiency of 92.94%, highlighting its potential for practical application. Through comprehensive mechanistic investigations, enhancing direct reduction process is considered the key to its high reduction efficiency with low formic acid . And the Lewis acidic adsorption sites enhance N 2 selectivity by enriching NO x − on the surface of the material. Overall, this study provides a novel approach for achieving efficient photocatalytic reduction of nitrate to N 2 under conditions with low concentration of hole scavengers.