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Liquid nitrogen ball-milled mechanochemical modification of starches with typically selected A, B and C crystal types on multiscale structure and physicochemical properties

Journal 2024 · IF 8.5 · 发表于 2024 年 9 月 4 日
作者: Chengyi Sun,Kai Du,Zhaoxian He,Zhijie Zhu,Yuqing Hu,Caihong Wang,Liping Mei,Qingling Xie,Yajie Chen,Yanyan Liu,Guangli Luo,Saddam Mustafa,Xu Chen,Xianfeng Du
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摘要

This study investigated the effect of liquid nitrogen ball-milled mechanochemical treatment on multiscale structure and physicochemical properties of starches with typically selected A (rice starch, ReS), B (potato starch, PtS) and C (pea starch, PeS) crystal types. The morphology of starch samples changed from integral granules to irregular fragments, and the interaction between the exposure O H bonds led to a serious agglomeration. As the treatment times extended, the crystalline structure of starch samples was gradually destroyed, and the excessive treatment approached amorphization. Moreover, the thermal stability of starch samples showed the downward tendency; and with amorphization increased, the swelling power (SP), solubility (S), water absorption capacity (WAC), oil absorption capacity (OAC) and hydrolysis rate of starch samples gradually increased. The obtained results provided a theoretical foundation for broadening the application range of ball-milled starches with different crystal types.

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