MOF-Mediated Construction of NiCoMn-LDH Nanoflakes Assembled Co(OH)F Nanorods for Improved Supercapacitive Performance

The application of transition metal hydroxides has long been plagued by its poor conductivity and stability as well as severe aggregation tendency. In this paper, a novel hierarchical core–shell architecture, using an F-doped Co(OH)2nanorod array (Co(OH)F) as the core and Mn/Ni co-doped Co(OH)2nanosheets (NiCoMn-LDH) as the shell, was constructed via an MOF-mediated in situ generation method. The obtained Co(OH)F@ NiCoMn-LDH composites exhibited excellent supercapacitive performance with large specific capacitance as well as improved rate capability and long-term stability. The effect of the Ni/Mn ratio on the supercapacitive performance and energy storage kinetics was systematically investigated and the related mechanism was revealed.