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Peroxymonosulfate Activation by MnO2/CoMoO4/NF for Degradation of Levofloxacin

Journal 2024 · IF 3.8 · 235(12): 1-14 · 发表于 2024 年 10 月 16 日
作者: Xing Yonglei,Liu Huijuan,Ha Yu,Jin Xiaoyong,Kou Beibei,Yang Rui,Ni Gang
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摘要

MnO 2 /CoMoO 4 / NF (Nickel foam) was obtained by loading MnO 2 onto the surface of CoMoO 4 /NF using electrodeposition. The results of degradation experiments showed that the degradation efficiency of levofloxacin (LVF) (15 ppm, pH = 6.12) over MnO 2 /CoMoO 4 //NF reached 80.4% in 30 min when the PMS concentration was 0.08 mM. When the pH was lower or higher than the pH value of the original solution, the performance of the material significantly decreased due to the repulsive effect between the catalyst and SO 5 2− . Cobalt and manganese ions exhibited a synergistic effect on the activation of PMS. The HCO 3 − ions showed the most significant inhibitory effect on the degradation of LVF. The free radical trapping experiments indicated that ·OH, and O 2 · − were the main active species in the degradation process of levofloxacin. The cyclic stability experiments proved the MnO 2 /CoMoO 4 /NF catalysts were efficient, stable and easy to recover. Graphical

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