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Preparation and properties of a metal-organic frameworks polymer material based on Sa-son seed gum capable of simultaneously absorbing liquid water and water vapor

Journal 2024 · IF 7.7 · 发表于 2024 年 5 月 7 日
作者: Xiaomei Liu,Xueqing Xu,Rongnian Xu,Na Wang,Fenghong Yang,Cailing Yang,Yanrong Kong,M. Iggy Litaor,Ziqiang Lei
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摘要

Atmospheric water harvesting (AWH) technology has attracted significant attention as an effective strategy to tackle the global shortage of freshwater resources. Work has focused on the use of hydrogel-based composite adsorbents in water harvesting and water conservation. The approaches adopted to make use of hygroscopic inorganic salts which subject to a “salting out” effect. In this study, we report the first use of modified UIO-66-NH 2 as a functional steric cross-linker and Sa-son seed gum was used as polymeric substrate to construct super hygroscopic hydrogels by free radical copolymerization. The maximum water uptake on SMAGs (572 cm 3 ·g −1 ) outperforms pure UIO-66-NH 2 (317 cm 3 ·g −1 ). Simultaneously, our first attempt to use it for anti-evaporation applications in an arid environment (Lanzhou, China) simulating sandy areas. The evaporation rate of the anti-evaporation material treated with 0.20 % super moisture-absorbent gels (SMAGs) decreased by 6.1 % over 64 h period under natural condition in Lanzhou, China. The prepared material can not only absorb liquid water but also water vapor, which can provide a new way for water collection and conservation technology. The design strategy of this material has wide applications ranging from atmospheric water harvesting materials to anti-evaporation technology.

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